Structuralism, as a mode of thinking and methodology, is quite important to analyze the theme and meaning. The director forms the binary oppositions of the surface structure by which the plot of the movie can be developed, so as to help construct the heroic image of Django and deepen its theme and connotation. The authors, by analyzing the binary oppositions in the film from the perspective of structuralism, tries to explore its deep underlying structure, unfolds the social meaning to the audience. This study offers a different perspective of appreciation of the film.