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DOI Prefix 10.20431 |
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International Journal of Advanced Research in Chemical Science
Volume-4 Issue-3, 2017, Page No: 24-28
Calixarene Based Artificial Selective Sites for the Specific Binding Some Mycotoxins
N.F. Starodub11*, V.M. Voitsitskiy1, V.M., V.P. Prokofiev1
1.National University of Leif and Environmental Sciences of Ukraine
2.Joint Research and Production Center 'Science" of Ukraine
2.Joint Research and Production Center 'Science" of Ukraine
Citation : N.F. Starodub, V.M. Voitsitskiy, V.M. V.P. Prokofiev, Calixarene Based Artificial Selective Sites for the Specific Binding Some Mycotoxins International Journal of Advanced Research in Chemical Science. 2017;4(3):24-28.
Abstract
Number of calix[4]rezortsynarenes with the different structures: R(H)-CH3, R(H)-C3H7, R (H)-C7H15, R(H)-C11H23 and R(OH)-C11H23 were selected by the computer modeling for the investigation of their absorption properties in respect of such mycotoxins as patulin, T2, aflatoxin B1 and zearelenon. It was found that all used calix[4]rezortsynarenes interact with the mentioned mycotoxins but the structure type R(H)-C11H23was characterized by the highest level of sorption activity. Based on the level of the concentration of the testedmycotoxins and on the determined association coefficient in the reaction of certain mycotoxins iththecalix[4]rezortsynarenes it should be considered that the level of specificity or too low, or nonexistent. Application of the calix[4]rezortsynarenes as selective sites can be recommended only for general screening the presence of mycotoxins in the environment.
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