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DOI Prefix 10.20431 |
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International Journal of Advanced Research in Chemical Science
Volume-3 Issue-9, 2016, Page No: 11-18
Sonochemical and Infrared Spectroscopies Study of Binary Liquid Mixture of O-Chlorotoluene and P-Chlorotolune with T-Butanol At 308.15 K and 313.15 K
Mehdi Hasan1*, N.A.Dokhe1**, A.B.Sawant1, P.S.Pawar1
P.G. Department of chemistry M.S.G. College, Malegaon camp 423105 M.S India
Citation : Mehdi Hasan, N.A.Dokhe, A.B.Sawant, P.S.Pawar, Sonochemical and Infrared Spectroscopies Study of Binary Liquid Mixture of O-Chlorotoluene and P-Chlorotolune with T-Butanol At 308.15 K and 313.15 K International Journal of Advanced Research in Chemical Science. 2016;3(9):11-18.
Abstract
Densities, ultrasonic velocities and Infra-red spectroscopes of binary liquid mixture of o-chlorotuluene and p-chlorotoluene with t-butanol have been measured at 308.15 and 313.15 K using these parameter the isentropic compressibilities (Ks) interrmolecular free length(Lf)have been calculated. Deviation in isentropic compressibilites(ΔKs)and Excess intermolecular free length(LfE)are interpreted in terms of hetroassociation. These Derived parameters have been used to study the intermolecular interaction in binary liquid mixtures. The theoretically calculated values of ultrasonic speed are derived by using free length theory. Collision factor theory, Nomoto’s and Van Dael’s equation were compared with those obtained experimentally.
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