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DOI Prefix 10.20431 |
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International Journal of Advanced Research in Chemical Science
Volume-1 Issue-4, 2014, Page No:29-34
An Environmentally Beningn Solvent Free Novel Methods for the Synthesis of Metal Complexes Using Imidazo[4,5-F] 1,10-Phenanthroline and their Derivatives and Biological Activities
Dr. Kabeer A Shaik1, Azeem Ahmed2
1.Organic Synthesis Laboratory, P.G. Department of Chemistry, Sir Sayyed College of Arts, Commerce and Science, Aurangabad, India
2.Organic Laboratory, MVS Government Degree and P.G. College, Mahabubnagar, India
2.Organic Laboratory, MVS Government Degree and P.G. College, Mahabubnagar, India
Citation : Dr. Kabeer A Shaik,Azeem Ahmed, An Environmentally Beningn Solvent Free Novel Methods for the Synthesis of Metal Complexes Using Imidazo[4,5-F] 1,10-Phenanthroline and their Derivatives and Biological Activities International Journal of Advanced Research in Chemical Science. 2014;1(4):29-34.
Abstract
MnL1,CuL1,CoL1,NiL1,CrL1,FeL1 and ZnL1 (L1 =[2,4,6-trihydroxy phenyl] Imidazo[4,5] 1,10-phenanthroline),MnL2,CuL2,CoL2,NiL2,CrL2,FeL2 and ZnL2 (L2 = (5-Bromo,3-Methoxy Phenyl) Imidazo [4,5] 1,10- Phenanthroline), MnL3,CuL3,CoL3,NiL3,CrL3,FeL3 and ZnL3 (L3=2,4,6-trifluro phenyl Imidazo [4,5] 1,10-phenanthroline), MnL4,CuL4,CoL4,NiL4,CrL4,FeL4 and ZnL4 (L4=4-ethyl phenyl Imidazo[4,5] 1,10-phenanthroline), MnL5,CuL5,CoL5,NiL5,CrL5,FeL5 and ZnL5 (L5=4-hydroxy,3,5-dimethyl phenyl Imidazo[4,5] 1,10-phenanthroline) complexes were synthesized. L1, L2,L3,L4 and L5 ligands were prepared by the condensation of 1,10-phenanthroline-5,6-dione with 2,4,6-Trihydroxy benzaldehyde, 5-Bromo,3-methoxy benzaldehyde ,2,4,6-Trifluro Benzaldehyde,4-Ethyl Benzaldehyde,4-Hydroxy 3,5-dimethyl Benzaldehyde respectively. The structures of the compounds were determined by elemental analyses, IR, UV-Visible, 1H-NMR and Mass Spectra. Antibacterial activity of the ligands and their metal complexes were tested against selected bacteria by disc diffusion method.
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