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  DOI Prefix   10.20431


 

International Journal of Advanced Research in Chemical Science
Volume-1 Issue-1, 2014, Page No:87-94

Structural and Electroluminescence Properties of Pure PVK and Doped Tio2polymer Thin Films

R.S.Sonone,V.M.Raut,G.H.Murhekar

1.Department of Chemistry Government Vidarbha Institute of Science and Humanities, Amaravati, India
2.Department of Chemistry Government Vidarbha Institute of Science and HumanitiesAmaravati, India
3.Department of Chemistry R.G.Rathod Arts and Science College Murtizapur Dist. Akola, India

Citation : R.S.Sonone,V.M.Raut,G.H.Murhekar, Structural and Electroluminescence Properties of Pure PVK and Doped Tio2polymer Thin Films International Journal of Advanced Research in Chemical Science. 2014;1(1):87-94.

Abstract


Polymeric thin films of poly (N-vinylcarbazole) (PVK) with nano-crystalline titanium oxide (TiO2) were fabricated by using bath deposition method. The X-ray diffraction (XRD) data revealed the amorphous nature of PVK polymer matrix and increased with increase of TiO2 concentration. The complexation of the polymer was confirmed by Fourier transform infrared (FTIR) and UV-Visible studies. The Electroluminescence (EL) spectra of the thin films of polyvinylcarbazole (PVK) with titanium oxide (TiO2) showed an enhancement in the electroluminescence properties with various molar concentration of dopant. Moreover, the TiO2 based Poly (N-vinylcarbazole) (PVK) exhibited a remarkable variation at higher molar concentration of the EL spectrum as compared to that of the pure polyvinylcarbazole film. The current-voltage characteristics of the various molar concentrations of TiO2 shows the same trained in comparison with EL.


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